I understand, I think. The Sentura II has been modified to have a grounded cord, and the 'death cap' has been disconnected, to the polarity switch has nothing to do. You want to add in the mid boost circuit that is on later models, using the polarity switch. Right?
I see no particular reason it wouldn't work. There could be an issue with a long wiring run in the vicinity of the power supply section. My Sentura II schematic doesn't have the mid boost circuit, but my Sentura II does. So, if no one else has a schematic, I might be persuaded to open mine up and trace the circuit out. Be warned, though, I'm a lazy old fuck, so it'd likely be a while, if I ever got to it at all!