if you ran a cab at 6 ohms along with a cab a 4ohms you'd be running a total load of 2.4 ohms.
which is cutting it close for vintage equipment. your head may be able to take it but i wouldn't suggest it.
i'm sure many people know more than myself on here but that's my opinion.
the math you'd have to do would look something like this.
4 ohms X 6 ohms = 24
4 ohms + 6 ohms = 10
then take you're answers and divide
24 / 10 = 2.4 ohm load total
i would suggest that if you do both cabs run the marshall at 16
if you do the same math with 4ohms and 16 ohms
the total load turns out to be 4.363
which would be much safer
i believe if you have a '79 concert lead (probably black face with red knobs) it's meant to run at 2ohms.
but i wouldn't push a 30 year old piece of equipment that far for such little payoff as well as possible heartbreak.
hope this was helpful.